Prof. Ali Coskun received his BSc in Chemistry from the Middle East

Transkript

Prof. Ali Coskun received his BSc in Chemistry from the Middle East
Prof. Ali Coskun received his BSc in Chemistry from the
Middle East Technical University (METU) in 2001. He
received his MSc and PhD degrees in Chemistry in the same
institution while carrying out his research activities under the
supervision of Professor Engin U. Akkaya. After his graduate
studies, He joined to the laboratory of Prof. J. Fraser Stoddart
as a research associate, first at University of California at Los
Angeles (UCLA) and subsequently at Northwestern
University. He next joined to the Graduate School of EEWS,
Department of Chemistry at Korea Advanced Institute of
Science and Technology (KAIST) as an assistant professor in
2012 and recently promoted to Associate Professor. He is
currently developing porous polymers for CO2 capture,
separation and conversion, naoporous carbon materials for H2
storage and energy storage applications, organic Li-ion batteries and also polymeric binders
for silicon anodes. Recently, he received highly prestigious “2013 Excellent New Researcher
Award in Chemistry" for the development of efficient gas storage materials. This prestigious
early career award is given to only one PI per funding cycle in the entire country at the
respective subject division.
Ali Coskun, PhD
Graduate School of EEWS (Energy Environment Water Sustainability)
Department of Chemistry and KI NanoCentury,
Korea Advanced Institute of Science and Technology (KAIST)
373-1 Guseong Dong, Yuseong Gu, Daejeon 305-701, Republic of Korea
Tel: +82-10-3308-8337, Office: +82-42-350-1724
Email: [email protected]
PROFESSIONAL POSITIONS
Associate Professor at the Graduate School of EEWS and Department of Chemistry
at the Korea Advanced Institute of Science and Technology (KAIST)
March 2015–Present
Organic Rechargeable Batteries • Supercapacitors • Organic Photovoltaics • Hydrogen Storage • CO2 Capture, Storage
and Conversion• Nanoporous Polymers • Methane Storage and Conversion • Microporous Carbon Materials
Assistant Professor at the Graduate School of EEWS and Department of Chemistry
at KAIST
March 2012–January 2015
Organic Rechargeable Batteries • Supercapacitors • Organic Photovoltaics • Hydrogen Storage • Carbon dioxide
Capture, Storage and Conversion• Nanoporous Polymers • Methane Storage and Conversion • Porous Carbon
Postdoctoral Research in Molecular Nanotechnology
October 2007–February 2012
Advisor: Professor J Fraser Stoddart, Department of Chemistry, Northwestern University
Mechanically Interlocked Molecules/Oligomers and Polymers • Functional Nanoparticles and Their Assemblies • MetalOrganic Frameworks • Molecular Flash Memory and Logic Gates • Energy Storage/Conversion
Graduate Student Research in Supramolecular Chemistry
September 2003–September 2007
Advisor: Professor Engin U Akkaya, Middle East Technical University (METU), Ankara, Turkey
PhD Thesis: “Ion Sensing and Molecular Logic in Supramolecular Systems”
Turkish Scientific and Research Council (TUBITAK) Research Fellow
September 2006–March 2007
Advisor: Professor J Fraser Stoddart, Department of Chemistry, University of California at Los Angles
Design and Synthesis of the Bistable [2]Rotaxanes and [2]Catenanes for Molecular Electronics Applications
Noncovalent Functionalization of Carbon Nanotubes • Functional Borromean Rings
•
Graduate Student Research in Supramolecular Chemistry
September 2001–August 2003
Advisor: Professor Engin U Akkaya, METU, Ankara, Turkey
MSc Thesis: “Novel Supramolecular Ion Sensing Systems and Their Application in Molecular Logic Gates”
EDUCATION
PhD in Organic Chemistry (The Language of Education is English), METU, Ankara, Turkey
MSc in Organic Chemistry (The Language of Education is English), METU, Ankara, Turkey
BS in Chemistry (The Language of Education is English), METU, Ankara, Turkey
2007
2003
2001
AWARDS AND HONORS
National Research Foundation of Korea, “Excellent New Researcher (우수신진) Award in Chemistry”
2013
Gordon Research Conference on Noble Metal Nanoparticles – Best Poster Award
2010
Mustafa N Parlar Education and Research Foundation, PhD Thesis of the Year Award (Campus-Wide)
2007
TUBITAK, PhD Fellowship (Nation-Wide)
2004-2007
TUBITAK, Young Scientist Training Program, Research Fellowship (Nation-Wide)
2006
1 President of the METU Graduate Student Council
2004
Mustafa N Parlar Education and Research Foundation, MSc Thesis of the Year Award (Campus-Wide)
2003
Member of the METU Graduate Student Council
2003
TUBITAK, MSc Fellowship (Nation-Wide) 2002-2003 Graduation Degree, High Honor Student (Ranked First)
2001
TEACHING EXPERIENCE
Instructor
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Delivered Graduate Level Lectures on Supramolecular Chemistry (Spring Semester)
Delivered Graduate Level Lectures on Nanomaterials for Photocatalysis (Fall Semester)
Delivered Graduate Level Lectures on Mechanostereochemistry (Fall Semester)
Instructor
•
•
•
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METU / September 2003-September 2007
Supervised Organic Chemistry Laboratory for 50 Students
Graded laboratory reports and examinations for the Organic Chemistry Laboratory Classes
Aided course instructor in the design of midterm and final examinations for both Organic Chemistry
and Organic Chemistry Laboratory Classes
Delivered occasional Organic Chemistry Lectures and Problem Solving Sessions
in place of the course instructor
Delivered occasional lectures on Supramolecular Chemistry in place of the course instructor
Graduate Student Instructor
•
•
Northwestern University/2011
Delivered occasional lectures on Mechanostereochemistry in place of course instructor
Graduate Student Instructor
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•
Korea Advanced Institute of Science and Technology/2012
METU / September 2001-September 2003
Supervised General Chemistry Laboratory for 70 Students
Graded laboratory reports and designed midterm and final examinations for
General Chemistry Laboratory Classes
Delivered occasional General Chemistry Lectures and Problem Solving Sessions
RESEARCH GRANTS
International
Team Projects
[1] High Performance Silicon Negative Electrodes for High Energy Density Lithium Battery Applications
Source of Support: Qatar National Research Fund (QNRF)
Funding Program: National Priorities Research Program (NPRP)
Total Award Amount (Team): $900,000
Total Award Amount (Individual): $150,000
Total Award Period Covered: 12/2014-11/2017
Status: Active
National
Team Projects
[2] Basic Research Laboratory (BRL) for Atomic Level Understanding of Energy Storage Systems
2 Source of Support: National Research Foundation (NRF)
Funding Program: BRL program
Total Award Amount (Team): 2,000,000,000 KRW
Total Award Amount (Individual): 500,000,000 KRW
Total Award Period Covered: 07/2014-06/2019
Status: Active
[3] CO2 Capture and Separation by Porous Polymers
Source of Support: Korea Advanced Institute of Science and Technology (KAIST)
Funding Program: Saudi Aramco-KAIST CO2 Management Center
Total Award Amount (Team): 1,200,000,000 KRW
Total Award Amount (Individual): 300,000,000 KRW
Total Award Period Covered: 10/2013-09/2016
Status: Active
Individual Projects
[4] Pillared Graphene Nanoarchitectures for Hydrogen Storage
Source of Support: National Research Foundation (NRF)
Funding Program: Excellent New Researcher (우수신진) Award in Chemistry
Total Award Amount: 550,000,000 KRW
Total Award Period Covered: 06/2013-05/2016
Status: Active
[5] Catalytic conversion of Carbon Dioxide to Methanol Using Porous Covalent Organic Polymers
Incorporating N-Heterocyclic Carbene Catalysts
Source of Support: Khalifa University (KUSTAR)-KAIST Institute
Funding Program: KUSTAR-KAIST Institute Matching Fund Program
Total Award Amount: 100,000,000 KRW
Total Award Period Covered: 01/2014-12/2015
Status: Active
Completed Projects
[1] Supercapacitors Based on Porous 3D-Graphene Nanoarchitectures
Source of Support: Korea Advanced Institute of Science and Technology (KAIST)
Funding Program: High Risk High Return (HRHR) Program
Total Award Amount: 30,000,000 KRW
Total Award Period Covered: 07/2012-06/2013
Status: Completed
[2] Catalytic conversion of Carbon Dioxide to Methanol Using Porous Covalent Organic Polymers
Incorporating N-Heterocyclic Carbene Catalysts
Source of Support: Korea Advanced Institute of Science and Technology (KAIST)
Funding Program: KUSTAR-KAIST Institute
Total Award Amount: 50,000,000 KRW
3 Total Award Period Covered: 10/2012-09/2013
Status: Completed
[3] Development of Novel Covalent Organic Polymers and Process Design Techniques for Energyefficient CO2 Capture
Source of Support: Korea Advanced Institute of Science and Technology (KAIST)
Funding Program: Hyundai Heavy Industries-EEWS Green Technology Center
Total Award Amount (Team): 360,000,000 KRW
Total Award Amount (Individual): 80,000,000 KRW
Total Award Period Covered: 10/2013-09/2014
Status: Completed
PUBLICATION LIST
[Google Scholar: Total citations: 3237, h-index: 29]
[Web of Science: Total citations: 3030, h-index: 28]
as of August 1, 2015
Researcher ID: C-1045-2008
Since the appointment at KAIST (* denotes corresponding author(s)):
[54] Buyukcakir, O†; Je, S. H.†; Park, J.; Patel, H. A.; Jung, Y.; Yavuz, C. T.*; Coskun, A* “Systematic
Investigation of the Effect of Polymerization Routes on the Gas Sorption Properties of Nanoporous
Azobenzene Polymers,” Chem. Eur. J., 2015, DOI: 10.1002/chem.201501233. († Equal Contribution)
[53] Mara, M. W.†; Bowman, D. N.†; Buyukcakir, O.†; Shelby, M. L.; Haldrup, K.; Huang, J.; Harpham, M. R.;
Stickrath, A. B.; Zhang, X.; Stoddart, J. F.; Coskun, A.*; Jakubikova, E.*; Chen, L. X.* “Electron
Injection from Copper Diimine Sensitizers into TiO2: Structural Effects and Their Implications for Solar
Energy Conversion Devices,” J. Am. Chem. Soc., 2015, 137, 9670–9684. († Equal Contribution)
[52] Buyukcakir, O.; Seo, Y.; Coskun, A.* “Thinking Outside the Cage: Controlling the Extrinsic Porosity and
Gas Uptake Properties of Shape Persistent Molecular Cages in Nanoporous Polymers,” Chem. Mater.,
2015, 27, 4149–4155.
[51] Song, K. S.; Coskun A.* “Catalyst-free Synthesis of Porous Graphene Networks as Efficient Sorbents for
CO2 and H2,” ChemPlusChem, 2015, 80, 1127–1132. (Early Career Series)
[50] Byun, Y.; Coskun, A.* “Bottom-up Approach for the Synthesis of a Three-Dimensional Nanoporous
Graphene Nanoribbon Framework and Its Gas Sorption Properties,” Chem. Mater., 2015, 27, 2576–2583.
[49] Jeong, Y. K.†; Kwon, T.-W†; Lee, I.; Kim, T.-S; Coskun, A*, Choi, J. W.* “Millipede-inspired Structural
Design Principles for High Performance Polysaccharide Binders in Silicon Anodes,” Energ. Environ.
Sci, 2015, 8, 1224-1230. († Equal Contribution)
[48] Kwon, T.-W†; Jeong, Y. K. †; Lee, I.; Kim, T.-S; Choi, J. W.*; Coskun, A* “Systematic Molecular-Level
Design of Binders Incorporating Meldrum`s Acid for Silicon Anodes in Lithium Rechargeable Batteries,”
Adv. Mater., 2014, 26, 7979–7985. [1] (†Equal contribution)
[47] Byun, J.; Je, S.-H; Patel, H. A.; Coskun, A.*, Yavuz, C. T.* “Nanoporous Covalent Organic Polymers
Incorporating Tröger’s Base Functionalities for Enhanced CO2 Capture,” J. Mater. Chem. A, 2014, 2,
12507–12512. [4]
[46] Kim, D. J.; Jung, Y. H.; Bharathi, K. K.; Je, S. H.; Kim, D. K.*; Coskun, A.*, Choi, J. W.* “An Aqueous
Sodium Ion Hybrid Battery Incorporating Organic Compound and Prussian Blue Derivative,” Adv. Energ.
Mater., 2014, 4, 1400133.
4 [45] Jeong, Y. K.†; Kwon, T.-W.†; Lee, I.; Kim, T.-S.; Coskun, A.*; Choi, J. W.* “Hyperbranched βCyclodextrin Polymer as an Effective Multidimensional Binder for Silicon Anodes in Lithium
Rechargeable Batteries,” Nano Lett., 2014, 14, 864–870. [9] (†Equal Contribution)
[44] Srinivasan, S.; Je, S. H.; Back, S.; Barin, G.; Buyukcakir, O.; Guliyev, R., Jung, Y.; Coskun, A.* “Ordered
Supramolecular Gels Based on Graphene Oxide and Tetracationic Cyclophanes,” Adv. Mater., 2014, 26,
2725–2729. [2]
[43] Fahrenbach, A. C.; Bruns, C. J.; Li, H.; Trabolsi, A.; Coskun, A., Stoddart, J. F.* “Ground-State Kinetics
of Bistable Redox-Active Donor–Acceptor Mechanically Interlocked Molecules,” Acc. Chem. Res., 2014,
47, 482–493.[7]
[42] Patel, H. A.; Je, S. H.; Park, J.; Jung, Y.; Coskun, A.*; Yavuz, C. T.* “Directing the Structural Features
of N2-Phobic Nanoporous Covalent Organic Polymers for CO2 Capture and Separation,” Chem. Eur. J.,
2014, 20, 772–780. [6]
[41] Cao, D.; Juríček, M.; Brown, Z. J.; Sue, A. C.-H.; Liu, Z.; Lei, J.; Blackburn, A. K.; Grunder, S.; Sarjeant,
A. A.; Coskun, A.; Wang, C.; Farha, O. K.; Hupp, J. T.; Stoddart, J. F. “Three-Dimensional Architectures
Incorporating Stereoregular Donor–Acceptor Stacks,” Chem. Eur. J., 2013, 19, 8457–8465. [5]
[40] Barin, G.; Frasconi, M.; Dyar, S. M.; Iehl, J.; Buyukcakir, O.; Sarjeant, A. A.; Carmieli, R.; Coskun, A.;
Wasielewski, M. R., Stoddart, J. F. “Redox-Controlled Selective Docking in a [2]Catenane Host,” J. Am.
Chem. Soc., 2013, 135, 2466–2469.[7]
[39] Patel, H. A.; Je, S. H.; Park, J.; Chen, D. P.; Jung, Y.; Yavuz, C. T.*; Coskun, A.* “Unprecedented Hightemperature CO2 Selectivity in N2-phobic Nanoporous Covalent Organic Polymers,” Nature
Commun., 2013, 4, 1357.[66] Highlighted in the Chemistry World on January 17, 2013, C&EN News on
January 21, 2013 and KAIST Breakthroughs Newsletter (Fall 2014)
[38] Schmucker, A. L.; Barin, G.; Brown, K. A.; Rycenga, M.; Coskun, A.; Buyukcakir, O.; Osberg, K. D.;
Stoddart, J. F.; Mirkin C. A. “Electronic and Optical Vibrational Spectroscopy of Molecular Tunnel
Junctions Created by On-Wire Lithography,” Small, 2013, 9, 1900–1903. [5]
[37] Srinivasan, S.; Shin, W. H.; Choi, J. W.; Coskun, A.* “A Bifunctional Approach to the Preparation of
Graphene and Ionic Liquid-Based Hybrid Gels,” J. Mater. Chem. A, 2013, 1, 43‒48. [7]
[36] Kim, D. J.; Je, S.-H.; Sampath, S.; Choi, J. W.*; Coskun, A.* “Effect of N-substitution in
Naphthalenediimides on the Electrochemical Performance of Organic Rechargeable Batteries,” RSC
Adv., 2012, 2, 7968‒7970. [12]
Before the appointment at KAIST:
[35] Huang, J.; Buyukcakir, O; Mara, M. W.; Coskun, A.; Dimitrijevic, N. M.; Barin, G.; Kokhan, O.;
Stickrath, A. B.; Ruppert, R.; Tiede, D. M.; Stoddart, J. F.; Sauvage, J.-P.; Chen, L. X. “Highly Efficient
Ultrafast Electron Injection from the Singlet MLCT Excited State of Copper(I) Diimine Complexes to
TiO2 Nanoparticles,” Angew. Chem. Int. Ed., 2012, 51, 12711–12715.[38]
[34] Coskun, A.; Spruell, J. M.; Barin, G.; Dichtel, W. R.; Flood, A. H.; Botros, Y. Y.; Stoddart, J. F. “High
Hopes: Can Molecular Electronics Realise its Potential?,” Chem. Soc. Rev., 2012, 41, 4827‒4859.
Highlighted as a front cover. [91] [33] Barin, G.; Coskun, A.; Foudah, M. M. G.; Stoddart, J. F. “Mechanically Interlocked Molecules
Assembled by π‒π Recognition,” ChemPlusChem, 2012, 77, 159‒185. [24] [32] Coskun, A.; Hmadeh, M.; Barin, G.; Gandara, F.; Li, Q.; Choi, E.; Strutt, N. L.; Cordes, D. B.; Slawin, A.
M. Z.; Stoddart, J. F.; Sauvage, J.-P.; Yaghi, O. M. “Metal-Organic Frameworks Incorporating CopperComplexed Rotaxanes,” Angew. Chem. Int. Ed., 2012, 51, 2160‒2163. [37] [31] Avellini, T.†; Hao, L.†; Coskun, A.†; Barin, G.; Trabolsi, A.; Basuray, A. N.; Dey, S. K.; Credi, A.; Silvi,
S.; Stoddart, J. F.; Venturi, M. “Photoinduced Memory Effect in a Redox Controllable Bistable Molecular
Switch,” Angew. Chem. Int. Ed., 2012, 51, 1611‒1615. [43] (†Equal Contribution)
5 [30] Fahrenbach, A. C.; Barnes, J. C.; Lanfranchi, D. A.; Li, H.; Coskun, A.; Gassensmith, J. J.; Liu, Z.;
Benitez, D.; Trabolsi, A.; Goddard, W. A.; Elhabiri, M.; Stoddart, J. F. “Solution-Phase Mechanistic
Study and Solid-State Structure of a Tris(Bipyridinium Radical Cation) Inclusion
Complex,” J. Am.
Chem. Soc. 2012, 134, 3061‒3072.[41]
[29] Coskun, A.; Banaszak, M.; Astumian, R. D.; Stoddart, J. F.; Grzybowski, B. A. “Great expectations: Can
Artificial Molecular Machines Deliver on Their Promise?,” Chem. Soc. Rev., 2012, 41, 19‒30.[221]
Highlighted as a front cover and also in Sciencenewsline on November 25, 2011, R&D Magazine on
November 28, 2011, AZO NANO on November 29, 2011 and C&EN News on April, 2 2012.
[28] Li, H.; Fahrenbach, A. C.; Coskun, A.; Zhu, Z.; Barin, G.; Zhao, Y.-L.; Botros, Y. Y.; Sauvage, J.-P.;
Stoddart, J. F. “A Light-Stimulated Molecular Machine Driven by Radical Pairing Interactions in Water, ”
Angew. Chem. Int. Ed., 2011, 50, 6782–6788. [55] Highlighted as an inside cover
[27] Dey, S. K.; Coskun, A.; Fahrenbach, A. C.; Barin, G.; Basuray, A. N.; Trabolsi, A.; Stoddart, J. F. “A
Redox-Active Reverse Donor-Acceptor [2]Rotaxane,” Chem. Sci., 2011, 2, 1046–1053. [22]
[26] Coskun, A.; Spruell, J. M.; Barin, G.; Fahrenbach, A. C.; Forgan, R. S.; Colvin, M. T.; Carmielli, R.;
Benítez, D.; Tkatchouk, E.; Friedman, D. C.; Sarjeant, A. A.; Wasielewski, M. R.; Goddard III, W. A.;
Stoddart, J. F. “Mechanically Stabilized TTF Radical Dimers,” J. Am. Chem. Soc., 2011, 133, 4538–4547.
[60] Highlighted in the Chemistry World on March 7, 2011.
[25] Basu, S.; Coskun, A.; Friedman, D. C.; Olson, M. A.; Benítez, D.; Tkatchouk, E.; Barin, G.; Yang, J.;
Fahrenbach, A. C.; Goddard, W. A.; Stoddart, J. F. “Donor Acceptor Oligorotaxanes Made to Order,”
Chem. Eur. J., 2011, 17, 2107–2119. [30] Highlighted in Angewantde Chemie (Angew. Chem. Int. Ed.,
2011, 50, 1466‒1468)
[24] Barin, G; Coskun, A.; Friedman, D. C.; Olson, M. A.; Colvin, M. T.; Carmielli, R.; Dey, S. K.; Bozdemir,
O. A.; Wasielewski, M. R.; Stoddart, J. F. “A Multistate Switchable [3]Rotacatenane,” Chem. Eur. J.,
2011, 17, 213−222. [32] Highlighted in the front cover of 2011 Year of Chemistry Issue.
[23] Han, S.; Wei, Y.; Valente, C.; Lagzi, I.; Gassenmith, J. J.; Coskun, A.; Stoddart, J. F.; Grzybowski, B. A.
“Chromatography in a Single Metal-Organic Framework (MOF) Crystal,” J. Am. Chem. Soc., 2010, 132,
16358–16361. [76] Highlighted in the Chemistry World on November 4, 2010.
[22] Han, S.; Wei, Y.; Valente, C.; Forgan, R. S.; Gassenmith, J. J.; Smaldone, R. A.; Nakanishi, H.; Coskun,
A.; Stoddart, J. F.; Grzybowski, B. A. “Imprinting Chemical and Responsive Micropatterns into MetalOrganic Frameworks,” Angew. Chem. Int. Ed., 2010, 50, 276−279. [22]
[21] Stephenson, R. M.;Wang, X.; Coskun, A.; Stoddart, J. F.; Zink, J. I. “Excited State Distortions Caused by
Photochemical Electron Transfer in a Donor-Acceptor [2]Rotaxane,” Phys. Chem. Chem. Phys., 2010, 12,
14135−14143. [7]
[20] Spruell, J. M.†; Coskun, A.†; Friedman, D. C.; Forgan, R. S.; Sarjeant, A. A.; Trabolsi, A.; Fahrenbach, A.
C.; Barin, G.; Paxton, W. F.; Dey, S. K.; Olson, M. A.; Benítez, D.; Tkatchouk, E.; Colvin, M. T.;
Carmielli, R.; Caldwell, S. T.; Rosair, G. M.; Hewage, S. G.; Duclairoir, F.; Seymour, J. L.; Slawin, A. M.
Z.; Goddard III, W. A.; Wasielewski, M. R.; Cooke, G; Stoddart, J. F. “Highly Stable TTF Radical Dimers
in [3]Catenanes,” Nature Chem., 2010, 2, 870−879. [71] (†Equal Contribution)
[19] Olson, M. A.; Coskun, A.; Fang, L.; Basuray, A. N.; Stoddart, J. F. “Polycatenation Under
Thermodynamic Control,” Angew. Chem. Int. Ed., 2010, 49, 3151−3156. [20]
[18] Coskun, A.; Wesson, P. J.; Klajn, R.; Trabolsi, A.; Fang, L.; Olson, M. A.; Dey, S. K.; Grzybowski, B.
A.; Stoddart, J. F. “Molecular-Mechanical Switching at the Metal Nanoparticle-Solvent Interface,” J. Am.
Chem. Soc., 2010, 132, 4310−4320. [36]
[17] Klajn, R.; Olson, M. A.; Wesson, P. J.; Fang, L.; Coskun, A; Trabolsi, A.; Stoddart, J. F.; Grzybowski, B.
A. “Dynamic Hook-and-Eye Nanoparticle Sponges,” Nature Chem., 2009, 1, 733−738. [50]
6 [16] Olson, M. A.; Coskun, A.; Klajn, R.; Fang, L.; Dey, S. K.; Browne, K.; Gryzbowski, B. A.; Stoddart, J. F.
“Assembly of Polygonal Nanoparticle Cluster Directed by Reversible Noncovalent Bonding Interactions,”
Nano Lett., 2009, 9, 3185–3190. [41]
[15] Guliyev, R.; Coskun, A.; Akkaya, E. U. “Design Strategies for Ratiometric Chemosensors: Modulation of
Excitation Energy Transfer at the Energy Donor Site,” J. Am. Chem. Soc., 2009, 131, 9007–9013. [122]
[14] Klajn, R.; Fang, L.; Coskun, A.; Olson, M. A.; Wesson, P. J.; Stoddart, J. F.; Grzybowski, B. A. “Metal
Nanoparticles Functionalized with Molecular and Supramolecular Switches,” J. Am. Chem. Soc., 2009,
131, 4233–4235. [69]
[13] Coskun, A.; Friedman, D. C.; Li, H.; Patel, K.; Khatib, H. A.; Stoddart, J. F., “A Light-Gated STOP-GO
Molecular Shuttle,” J. Am. Chem. Soc., 2009, 131, 2493–2495. [66]
[12] Patel, K.; Angelos, S.; Dichtel, W. R.; Coskun, A.; Yang, Y. W.; Zink, J. I.; Stoddart, J. F., “EnzymeResponsive Snap-Top Covered Silica Nanocontainers,” J. Am. Chem. Soc., 2008, 130, 2382–2383. [325]
[11] Coskun, A.; Saha, S.; Aprahamian, I.; Stoddart, J. F. “A Reverse Donor-Acceptor Bistable [2]Catenane,”
Org. Lett., 2008, 10, 3187–3190. [36]
[10] Coskun, A.; Yilmaz, M. D.; Akkaya, E. U., “Bis(2-pyridyl)-Substituted Boratriazaindacene as an NIREmitting Chemosensor for Hg(II),” Org. Lett., 2007, 9, 607–609. [166] – Highlighted as one of the most
cited Organic Letters article in 2007.
[9] Coskun, A.; Deniz, E.; Akkaya, E. U., “A Sensitive Fluorescent Chemosensor for Anions Based on a
Styryl-Boradiazaindacene Framework,” Tetrahedron Lett., 2007, 48, 5359–5361. [18]
[8] Coskun, A.; Yilmaz, M. D.; Akkaya, E. U., “An Acenaphthopyrrolone-Dipicolylamine Derivative as a
Selective and Sensitive Chemosensor for Group IIB Cations,” Tetrahedron Lett., 2006, 47, 3689–3691. [5]
[7] Coskun, A.; Akkaya, E. U., “Signal Ratio Amplification via Modulation of Resonance Energy Transfer:
Proof of Principle in an Emission Ratiometric Hg(II) Sensor,” J. Am. Chem. Soc., 2006, 128, 14474–
14475. [295]
[6] Coskun, A.; Akkaya, E. U., “Ion Sensing Coupled to Resonance Energy Transfer: A Highly Selective and
Sensitive Ratiometric Fluorescent Chemosensor for Ag(I) by a Modular Approach,” J. Am. Chem. Soc.,
2005, 127, 10464–10465. [302]
[5] Coskun, A.; Deniz, E.; Akkaya, E. U., “Effective PET and ICT Switching of Boradiazaindacene
Emission: A Unimolecular, Emission-mode, Molecular Half-subtractor with Reconfigurable Logic Gates,”
Org. Lett., 2005, 7, 5187–5189. [200]
[4] Coskun, A.; Deniz, E.; Akkaya, E. U., “Cation Modulation of Carbonyldipyrrinone (CDP) Fluorescence:
Emission-Ratiometric Sensing of Calcium,” J. Mater. Chem., 2005, 15, 2908–2912. [9]
[3] Coskun, A.; Akkaya, E. U., “Three-Point Recognition and Selective Fluorescence Sensing of L-DOPA,”
Org. Lett., 2004, 6, 3107–3109. [37]
[2] Coskun, A.; Akkaya, E. U., “Difluorobora-s-Diazaindacene Dyes as Highly Selective Dosimetric
Reagents for Fluoride Anions,” Tetrahedron Lett., 2004, 45, 4947–4949. [81] [1] Coskun, A.; Baytekin, B. T.; Akkaya, E. U. “Novel Fluorescent Chemosensor for Anions via Modulation
of Oxidative PET: a Remarkable 25-fold Enhancement of Emission,” Tetrahedron Lett., 2003, 44, 5649–
5651. [53]
PATENTS
[3]
Jeong, Y.-K; Kwon, T.W.; Coskun, A; Choi, J. W. “Binders for Lithium ion battery, manufacturing and
method,” Korean Patent (10-2013-0125838), 2013
7 [2]
[1]
Byun, J.; Je, S.H,; Patel, H.A.; Coskun, A.; Yavuz, C.T. “Tröger’s base linked covalent organic polymers
and its applications,” Korean Patent (10-2013-0146605), 2013.
Patel, H.A.; Je, S.H.; Yavuz, C.T.; Coskun, A. “Azo-covalent organic porous polymers and its synthesis
method,” Korean Patent (10-2013-0001436), 2013.
PRESENTATIONS
INVITED TALKS
08/2015
05/2015
03/2015
12/2014
11/2014
10/2014
09/2014
08/2014
08/2014
06/2014
10/2013
09/2013
08/2013
05/2013
12/2012
Singapore National Institute of Chemistry, Golden Jubilee Chemistry Conference,
Singapore “Nanoporous Polymers For Efficient CO2 Capture and Separation”
Northwestern University, Center for the Chemistry of Integrated Systems, Evanston, IL
“Nanoporous Polymers For Efficient CO2 Capture, Separation and H2 Storage”
International Symposium on Advanced Functional Materials, Hanbat University,
Daejeon, Republic of Korea “Systematic Design of Polymeric Binders For Silicon Anodes in
Lithium Rechargeable Batteries” 27th Korea Academy of Science and Technology Prestige Workshop, Seoul, Republic of
Korea “Bridging the Gap Between Crystalline and Amorphous Porous Materials by Using
Shape Persistent Organic Cages as Building Blocks”
EEWS 2014 – Advanced Technology For Next Generation Energy Storage Systems,
Daejeon, Republic of Korea “Systematic Design of Polymeric Binders for Silicon Anodes in
Lithium Rechargable Batteries”
Graphene and Related Technologies: from Laboratory to Industry – 2014, Istanbul,
Turkey “The Ordered Supramolecular Assembly of Reduced Graphene Oxide with
Tetracationic Cyclophanes”
4th International Conference on Metal-Organic Frameworks and Open Framework
Compounds, Kobe, Japan “Directing Structural Features and Gas Sorption Properties of
Covalent Amorphous Polymers”
248th ACS National Meeting, San Francisco, CA “Systematic Design of Polymeric Binders
for Silicon Anodes in Lithium Rechargeable Batteries”
University of California, San Diego (UCSD), Department of Chemistry, La Jolla, CA
“Directing Structural Features and Gas Sorption Properties of Covalent Amorphous Polymers”
2014 Korea – Japan Symposium on Frontier Photoscience, Seoul, Republic of Korea
“Ordered Supramolecular Gels Based on Graphene Oxide and Tetracationic Cyclophanes”
2nd International Workshop on CO2 Capture and Separation by Porous Solids, Daejeon,
Republic of Korea “CO2-philicity & N2-phobicity: Can They Coexist in Porous Polymers?”
KAIST Institute for the NanoCentury, Open Seminar, Daejeon, Republic of Korea
“Functional Materials Based on Integrated Molecular and Supramolecular Systems”
Northwestern University, Center for the Chemistry of Integrated Systems, Evanston, IL
“Porous Polymers for CO2 Capture&Separation”
NYU Abu Dhabi, Department of Chemistry, Abu Dhabi, United Arab Emirates
“Porous Covalent Organic Polymers for CO2 Capture&Separation”
Sogang University, Department of Chemistry, Seoul, Republic of Korea
“Functional Materials Based on Integrated Molecular Systems”
8 11/2012
05/2012
01/2012
03/2011
01/2011
01/2011
01/2011
11/2010
11/2010
12/2010
10/2010
EWHA Women`s University, Department of Chemistry, Seoul, Republic of Korea
“A Non-Covalent Approach to the Preparation of Porous Graphene Oxide Hybrid Gels”
Northwestern University, Center for the Chemistry of Integrated Systems, Evanston, IL
“Effect of N-substitution in Naphthalenediimides on the Electrochemical Performance
of Organic Rechargeable Batteries”
Indiana University, Department of Chemistry, Bloomington, IN
“Functional Materials Based on Integrated Molecular Systems”
Korea Advanced Institute of Science and Technology, Graduate School of EEWS,
Daejeon, Korea “Towards Integrated Systems in Chemistry”
University of Delaware, Newark, DE
“Towards Integrated Systems in Chemistry”
University of Chicago, Chicago, IL
“Towards Integrated Systems in Chemistry”
University of Notre Dame, Notre Dame, IN
“Towards Integrated Systems in Chemistry”
Milliken Research Corporation, Spartanburg, SC
“Towards Integrated Systems in Chemistry”
The Dow Chemical Company, Midland, MI
“Towards Integrated Systems in Chemistry”
University of Pittsburgh, Pittsburgh, PA
“Towards Integrated Systems in Chemistry”
Carnegie Mellon University, Pittsburgh, PA
“Towards Integrated Systems in Chemistry”
CONFERENCES
08/2014
03/2014
03/2014
03/2014
08/2013
09/2012
08/2010
06/2010
06/2010
248th ACS National Meeting, San Francisco, CA “Directing Structural Features and Gas
Sorption Properties of Covalent Amorphous Polymers” (Oral Presentation)
247th ACS National Meeting, Dallas, TX “Hyperbranched Polymers as Effective
Multidimensional Binders for Silicon Anodes in Lithium Rechargeable Batteries” (Oral
Presentation)
247th ACS National Meeting, Dallas, TX “Porous Covalent Amorphous Polymers for Efficient
CO2 Capture and Separation” (Oral Presentation)
247th ACS National Meeting, Dallas, TX “Non-covalent Approach to the Preparation of Porous
Graphene Oxide Supramolecular Gels” (Oral Presentation)
IUPAC 44th World Chemistry Congress, Istanbul, Turkey
“Porous Covalent Organic Polymers for CO2 Capture&Separation” (Oral Presentation)
5th International Conference on Advanced Lithium Batteries for Automobile Applications,
Istanbul, Turkey “Structural Effects on the Electrochemical Performance of Organic
Rechargeable Batteries” (Poster)
240th American Chemical Society National Meeting, Boston, MA “Multistate [3]catenanes
utilizing highly stable TTF radical dimers” (Oral Presentation)
Gordon Research Conference on Noble Metal Nanoparticles, Mount Holyoke College,
South Hadley, MA “Template-Directed Nanoparticulate Assemblies” (Poster)
The Fifth Joint International Symposium on Macrocyclic & Supramolecular Chemistry,
Nara, Japan “Highly Stable TTF Radical Dimers in [3]Catenanes” (Poster)
9 04/2010
09/2009
06/2009
08/2008
06/2007
06/2006
07/2005
08/2003
09/2003
The 7th Foundations of Nanoscience Conference, Snowbird, Utah
“Molecular-Mechanical Switching at the Nanoparticle-Solvent Interface” (Poster)
2nd Annual Postdoctoral Research Symposium, Argonne National Laboratory, Chicago, IL
“Nanoparticulated Switches and Their Assemblies,” (Oral Presentation)
The Fourth Joint International Symposium on Macrocyclic & Supramolecular Chemistry,
Maastricht, The Netherlands “Light-Gated Stop-Go Molecular Shuttles and Switches” (Poster)
236th American Chemical Society National Meeting, Philadelphia, PA
“Molecular Logic for Nanoelectronics” (Oral Presentation)
Joint International Symposium on Macrocyclic and Supramolecular Chemistry, Salice
Terme, Italy “ Design Strategies for Ratiometric Fluorescent Chemosensors,” (Poster)
Joint International Symposium on Macrocyclic and Supramolecular Chemistry, Victoria,
Canada “Signal Ratio Amplification via Modulation of Resonance Energy Transfer,” (Poster)
XXX International Symposium on Macrocyclic Chemistry, Dresden, Germany
“Molecular Half Subtractor Based on Boradiazaindacene Emission via PET and ICT Processes
Within a Single Molecule,” (Poster)
8th Conference on Methods and Applications of Fluorescence, Prague, Czech Republic
“Towards Novel Fluorescent Chemosensors for Anions”, (Poster)
XVII. National Chemistry Conference, Istanbul, Turkey “Application of New Boradiaza-sindacene Derivatives in Anion sensing and Molecular Logic Gates,” (Poster)
PROFESSIONAL MEMBERSHIP AND ACTIVITIES
2010
Member of the Local Committee for the Memorial Day Symposium, Evanston
2009-Present Materials Research Society Member
2008-Present Reviewer for Nature Communications, Angewandte Chemie, Journal of the American Chemical
Society, Advanced Materials, Advanced Energy Materials, Chemistry of Materials, Small,
Chemical Communications, Organic Letters, Analyst, CrystEngComm, ChemSusChem, Journal of
Materials Chemistry, Journal of Nanoparticle Research, Journal of Solid State Electrochemistry
2008-Present American Chemical Society Member
2007-2012
Writing grant reports for AFSOR-MURI, DOD, DOE, NSF
2007-2012
Writing of research grants for AFSOR-MURI, DOD, DOE, DTRA, NSF
2007-2012
Assistant to Fraser Stoddart as Theme Leader within the Functional Engineered Nano
Architectonics (FENA) Center
2004-2005
Elected President of METU Graduate Student Council, Organized Several Seminars to Improve
the Quality of the Graduate Level Education in Turkey
2003-2005
Designed and Performed Chemistry Experiments for High-School Students to Promote
Chemistry in Turkey
MENTORED STUDENTS/POSTDOCS
Korea Advanced Institute of Science and Technology
The following research personnel have been/are independently supervised by me:
[1]
[2]
[3]
[4]
Dr Srinivasan Sampath
Dr Hasmukh Patel
Sang Hyun Je
Taewoo Kwon
[5] Yearin Byun
[6] Dr Onur Buyukcakir
(03/2012-03/2014)
(03/2012-present)
(03/2012-present)
(09/2012-12/2013)
(03/2014-present)
(2013-present)
(10/2013-present)
Postdoctoral Fellow
Postdoctoral Fellow (co-advisor)
Ph.D Student
M.Sc. Student
Ph.D. Student
M.Sc. Student
Postdoctoral Fellow
10 [7] Daniel Kim
[8] Kyung Seob Song
[9] Dr Siddulu N. Talapaneni
[10] Kahee Kim
[11] Yoon Jeong Lee
(06/2013-09/2013)
(03/2014-present)
(07/2014-present)
(09/2014-present)
(03/2015-present)
Visiting Scholar
M.Sc. Student
Postdoctoral Fellow
M.Sc. Student
M.Sc. Student
COLLABORATORS
Lin X Chen (Northwestern University)
Jang Wook Choi (KAIST)
Alberto Credi (University of Bologna)
Yousung Jung (KAIST)
Jean-Pierre Sauvage (Université de Strasbourg / France − Northwestern University)
Ali Trabolsi (NYU Abu Dhabi)
Cafer T. Yavuz (KAIST)
11 

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