TIG BOMAR - Nitty

NITTY-GRITTY S.R.L.
Tig.Bomar - TIG BOMAR
Revision nr.1
Dated 30/10/2012
Printed on 4/12/2012
Page n. 1
2/7
3
4
5
6
7
0
EN
Safety Data Sheet
Hazard
Wear
The
information
protective
statements:
airtight
contained
goggles
in products.
the
(ref.present
standardsheet
EN 166).
are based on our own knowledge on the date of the last version. Users must verify the
10.6.
5.3.
Transport
Advice
Hazardous
for
byfirefighters.
air:
decomposition
H319
Causes
eye
irritation.
SKIN
suitability
PROTECTION
and
ofserious
provided
according
to dangerous
each specific
use of may
the product
.
GENERAL
In
the
event
INFORMATION
ofthoroughness
thermal
decomposition
orinformation
fire,
vapours
potentially
to health
be released.
Causes
skinlong-sleeved
irritation.
Wear
IATA:
This
document
category
must
II professional
be regarded
as NA
a guarantee
on and
any
specific
safety
footwear
product property.
(ref.and
Directive
89/686/CEE of
andsubstances
standard EN
344). Wash
body with
UseH315
jets
of water
tonot
cool
the
containers
tooveralls
prevent
product
decomposition
the development
potentially
hazardous
for
1. Identification of the substance/mixture and of the company/undertaking
soap
The
use
and
water
of this
after
product
removing
is not
overalls.
subject
our direct
control;
therefore, water
users must,
under ittheir
own
responsibility,
the current
health
health.
PHOSPHORIC
Always
ACID:
wear
phosphorus
full fire
prevention
oxide. togear.
Collect
extinguishing
to prevent
from
draining
into thecomply
sewerwith
system.
Dispose
of
Precautionary
statements:
RESPIRATORY
and
safety
laws
and
PROTECTION
regulations.
The
producer
is
relieved
from
any
liability
arising
from
improper
uses.
contaminated
water
used
for
extinction
and
the
remains
of
the
fire
according
to
applicable
regulations.
15. Regulatory
information.
1.1.
Product identifier
P264
Wash
. . . thoroughly
after
handling.
the
threshold
value
(ifEQUIPMENT
available)
for
one
or
more of the substances present in the preparation for daily exposure in the workplace or to a
SPECIAL
PROTECTIVE
FOR
FIRE-FIGHTERS
11.If
Toxicological
information.
P280
Wear
protective
gloves
/ protective
/ eyeservice
protection
/ face
protection.
Changes
fraction
established
to
previous
review:
by
the
company’s
prevention
andclothing
protection
is exceeded,
wear
a mask
withwaist),
an B or
universal
the class
(1, 2
Hardhat
with
visor,
fireproof
clothing
(fireproof
jacket
and
trousers
with straps
around
arms,
legs and
work
gloves filter,
(fireproof,
cut proof
Code:
Tig.Bomar
P302+P352
IFwere
ON SKIN:
Wash
with
plenty
of soap
and water.
The
or
3)
following
of
which
sections
must
be
chosen
modified:
according
to
the
limit
concentration
of
use
(ref.
standard
EN 141).
and
antistatic),
a
depressurised
mask
with
facemask
covering
the
whole
of
the
operator’s
face
or a self-respirator (self-protector) in the event
11.1.
15.1.
Information
Safety,
health
on
and
toxicological
environmental
effects.
regulations/legislation
specific
for
the
substance
or
mixture.
Product
name
TIG
BOMAR
P332+P313
If skin irritation occurs: Get medical advice / attention.
02
The
/ 14.
use
of respiratory
tract protection
such
as masks edema,
like thatpain
indicated
above, is necessary
to with
reduce
exposure
in the
of
large
quantities
of fume.
Acute
effects:
stinging
eyes.
Symptomsequipment,
may include:
rubescence,
and lachrymation.
Contact
skinworker
may cause:
irritation,
absence
of
technical
measures.
The
protection
provided
byand
masks
isadvised
inmay
any slightly
case
limited.
Seveso
category.
None.
erythema,
edema,
dryness
and
chapped
skin.
Vapour
inhalation
irritate the upper respiratory tract. Ingestion may cause health
1.2.
Relevant
identified
uses
of
the
substance
or
mixture
uses
against
2.3. Other hazards.
If
the substance
instomach
question
is and
odourless
or its olfactory
threshold is higher than the relative exposure limit and in the event of an emergency,
including
pain
sting, nausea
and sickness.
6. disorders,
Accidental
release
measures.
Restrictions
relating tolevels
the product
or contained
pursuantfor
to cleaning/passivation
Annex
ECworkplace
Regulation
1907/2006.
or when use
exposure
are unknown
or substances
the concentration
of
oxygenXVII
in tothe
is less steel
than weldings
17% volume, wear self-contained,
Intended
Electrolyte
of stainless
Information
not available.
Product. precautions,
open-circuit
compressed
air breathing
apparatus
standardprocedures.
EN 137) or fresh air hose breathing apparatus for use with full face mask, half
ACID
6.1.PHOSPHORIC
Personal
protective
equipment
and(ref.
emergency
Point.
3 standard
mask
or
mouthpiece
(ref.
EN 138).
LD50
(Oral):
1530
mg/kg
Rat individuals who are not suitably equipped. Use breathing equipment if fumes or powders
appropriate
protective
equipment.
Send
away
1.3.Wear
Details
of the supplier
of the
safety
data
sheet
3. LC50
Composition/information
on ingredients.
(Inhalation):
0,85 mg/l/1h
Ratis no hazard. Do not handle damaged containers or the leaked product before donning
are
released
into the air. Block
the >
leakage
if there
inprotective
Candidate gear.
List (Art.
REACH).
LD50
(Dermal):
2740 mg/kg
Rabbit
appropriate
For59information
on risks
for the environmental and health, respiratory tract protection, ventilation and personal
9. Substances
Physical
and
chemical
properties.
3.1.None.
Substances.
CITRIC
protection
equipment, refer to the other sectionsNITTY-GRITTY
of this sheet. S.R.L.
These indications apply for both processing staff and those involved in
Name ACID
LD50
(Oral):procedures.
3000 mg/kg
Rat DEI MARMORARI 36
9.1.emergency
Information
on basic physical and chemical
properties.
Full
address
VIA
Information not relevant.
SODIUM
CITRATE
Appearance
liquid
District and
Country
41057 SPILAMBERTO
(MO)
Substances subject to authorisarion (Annex XIV REACH).
(Oral):
1700 mg/kg light
Rat green
Colour
6.2.LD50
Environmental
precautions.
ITALIA
3.2.None.
Mixtures.
The
ground water and neighbouring areas. Dilute the product well with water after
Odourproduct must not penetrate the sewers, surface
odourless
Tel. water,
+39059785210
collection.
Odour
threshold.
Not
Fax available.
+390597861612
12.Contains:
Ecological
information.
pH.
Not available.
e-mail address of the competent person
Healthcare controls.
Melting
freezing
point.
Not
available.
6.3.Use
Methods
and
material
for
containment
and practices.
cleaning
up.
responsible
for the
Safety
Data
thisor product
according
toSheet
good working
Avoid littering. Inform the competent authorities, should the product reach waterways or
[email protected]
Workers
exposed to thisConc.
chemical
must not 67/548/EEC.
undergo health checks, provided that
available risk-assessment
data prove that the risks
Identification.
%. agent
Classification
Classification
1272/2008 (CLP).
For
liquid
products,
into
a suitable container
of material not incompatible with the product) and soak up any leaked product with
Initial
boiling
point. suck
Not(made
available.
sewers
or contaminate
soil or
vegetation.
related to the workers' health and safety are modest and that the 98/24/EC directive is respected.
absorbent
inert
material
(sand,
vermiculite,
diatomeous
earth,
Kieselguhr,
etc).
Collect
the
majority
of
the
remaining
material and deposit in
Boiling
range.
Not
available.
1.4. Emergency telephone number
PHOSPHORIC ACID
containers
spark proof
Flash
point. for disposal. For solid products, >use 60
°C. mechanical tools to collect the leaked product and place in plastic containers. If
12.1.
Toxicity.
C R34, Note B
Skin Corr. 1B H314, Note B
13,5 - 15
CAS.
7664-38-2
15.2.
Chemical
safety assessment.
there
are inquiries
no
contraindications,
use jets of waterNot
to available.
eliminate product residues. Make sure the leakage site is well aired. Contaminated
Evaporation
Rate
For
urgent
refer to
Information
not
available.
+393385767602
EC.
231-633-2
material
should
be disposed
of in compliance with the
provisions
Flammability
of solids
and gases
Not
available.set forth in point 13.
No
chemical
safety assessment has been processed for the mixture and the substances it contains.
INDEX.
015-011-00-6
inflammability
limit.
Not available.
12.2.
Persistence
and degradability.
2. Lower
Hazards
identification.
CITRIC ACID
inflammability
Not available.
6.4.Upper
Reference
to available.
otherlimit.
sections.
Information
not
Xi R37/38, Xi R41
Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335
4 - 4,5
CAS.
77-92-9
16.Any
Other
information.
information
on
personal protection and disposal Not
is given
in sections 8 and 13.
Lower
explosive
limit.
available.
EC.
201-069-1
Upper
explosive limit.
Not available.
12.3.
Bioaccumulative
potential.
2.1.
Classification
of the
substance or mixture.
INDEX.
Text
of hazard
(H) indications mentioned in section 2-3
the sheet:
pressure.
Notofavailable.
Information
not available.
7. Vapour
Handling
and
storage.
Vapour
density
Not
available.
T+
=
Very
Toxic(T+),
T
=
Toxic(T),
Xn
=
Harmful(Xn),
C
=
Corrosive(C),
Xi
=
Irritant(Xi),
O = Oxidizing(O),
= Explosive(E),
= Extremely Flammable(F+),
F = Highly
Flammable(F),
N=
TheSkin
product
is
as hazardous
pursuant
to the
provisions
set forthE in
Directives F+
67/548/EEC
and 1999/45/EC
and/or
EC Regulation
Corr.
1B classified
Skin corrosion,
category
1B 1,16
Dangerous
for the Environment(N)
Specific
gravity.
Kg/l
12.4.
Mobility
in
soil.
7.1.
Precautions
for
safe
handling.
1272/2008
(CLP)
(and
subsequent
amendments
and
supplements).
The
product
thus
requires
a
safety
datasheet
that
complies
with
the
Eye Dam. 1
Serious eye damage, category 1
Solubility
soluble
water
Information
Before
the
product,
consult
all the
sections
ofinthis
material safety data sheet. Do not eat, drink or smoke during use.
provisions
ofnot
EC
Regulationn
1907/2006
andother
amendments.
Skinhandling
Irrit.
2 available.
Skin irritation,
category
2subsequent
Partition
coefficient:
n-octanol/water
Not is
available.
The
full
wording
of the
Riskconcerning
(R) and hazard
(H) phrases
given in
section
16 of the
sheet.
Any
additional
the risks
for-health
the
environment
STOT
SE 3 information
Specific
target organ
toxicity
single and/or
exposure,
category
3 are given in sections 11 and 12 of this sheet.
Ignition
temperature.
Not
available.
12.5.
Results
of
PBT
and
vPvB
assessment.
7.2.
Conditions
for
safe
storage,
including
any
incompatibilities.
H314
Causes severe skin burns and eye damage.
Not available.
Information
not temperature.
available.
Normal
storage
conditions
without
particular
incompatibilities.
4. Decomposition
First
H318
aid
measures.
Causes
serious
eye damage.
Viscosity
Not available.
H315
Causes
skin
irritation.
2.1.1. Regulation 1272/2008 (CLP) and following amendments
and adjustments.
Reactive
H335 Properties
May
respiratory irritation.Not available.
12.6.
Other
adverse
effects.
7.3.
Specific
endof
use(s).
4.1.
Description
first
aid cause
measures.
Information
notcopiously
available.
EYES:
Irrigate
clean, fresh water for at least 15 minutes.
Hazard
classification
andwith
indication:
9.2.Seek
Other
information.
advice.
Text
ofmedical
risk
(R)
phrases
mentioned
in section 2-3 of the sheet:
Eye
Irrit.
2
H319
Immediately
with plenty
of water. Remove all contaminated clothing. Obtain immediate medical attention. Wash contaminated
Skincontrols/personal
Irrit. 2 wash H315
8. SKIN:
13.
Exposure
Disposal
considerations.
protection.
Information
not available.
R34 separately
CAUSES
clothing
before
usingBURNS.
them again.
R36/38
IRRITATING
EYES
AND
SKIN.andoradjustments.
Remove
to and
openfollowing
air.TO
If breathing
is irregular
stopped, administer artificial respiration. Obtain immediate medical attention.
2.1.2.
8.1.INHALATION:
13.1.
Control
Waste
Directive
treatment
parameters.
67/548/EEC
methods.
amendments
R37/38 and
IRRITATING
TO RESPIRATORY
SYSTEM
AND
SKIN.
INGESTION:
immediate
attention.
vomiting
only hazardous
if indicated waste.
by the doctor.
Give level
nothing
by mouth
to an unconscious
10.Reuse,
Stability
reactivity.
when Obtain
possible.
Product medical
residues
should beInduce
considered
special
The hazard
of waste
containing
this product
R41
RISK OF SERIOUS
DAMAGE
TO
EYES.
person.
Xi
Danger
Symbols:
should be
evaluated according to applicable
regulations. Type
Name
CountryTWA/8h
STEL/15min
10.1.
Reactivity.
Disposal
must be performed through an authorised waste management firm, in compliance
withppm
nationalmg/m3
and local regulations.
mg/m3
ppm
There
are
no particular
risks ofand
reaction
withboth
otheracute
substances
in normal conditions of use.
4.2.R
Most
important
symptoms
effects,
and delayed.
36/38
phrases:
CONTAMINATED
PACKAGING
GENERAL
BIBLIOGRAPHY
For symptoms
and
effectsmust
caused
by the contained
substances
see chap. 11.
Contaminated
packaging
be recovered
or disposed
of
in compliance
with national
waste management
PHOSPHORIC
ACID
TLV-ACGIH
1
3 regulations.
1.
Directive
1999/45/EC
and following amendments
PHOSPHORIC
temperatures
overis200°C.
The
full wordingACID:
of the decomposes
Risk (R) and at
hazard
(H) phrases
OEL
given in sectionEU
16 of the
1 sheet.
2
2.Indication
Directive 67/548/EEC
and following
amendments
andspecial
adjustments
4.3.
ofinformation.
any immediate
medical
attention and
needed.
OEL treatment
IRL
1
2
14.3.Transport
Regulation
(EC)
1907/2006
(REACH)
of
the
European
Parliament
not
available.
10.2.
Chemical
stability.
WEL
UK
1
2
2.2.Information
Label
elements.
4. Regulationis(EC)
1272/2008
of theofEuropean
Parliament
The
normal(CLP)
conditions
useprovisions
and storage.
The product
product isstable
not in
dangerous
under current
of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail
5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament
pursuant Maritime
to EC Regulation
1272/2008
(CLP)(IMDG),
and subsequent
supplements.
5. Hazard
Firefighting
measures.
(RID),
oflabelling
the International
Dangerous
Goods Code
and of theamendments
Internationaland
Air Transport
Association (IATA) regulations.
6.
Regulation
(EC)
453/2010
of
the
European
Parliament
10.3.Exposure
Possibility
of hazardous reactions.
8.2.
controls.
7. The
Merck Index.
- 10th Edition
hazardous
Hazard
pictograms:
5.1.No
Extinguishing
media. are foreseeable in normal conditions of use and storage.
Road
and
rail reactions
transport:
8. Handling Chemical Safety
As
the useEXTINGUISHING
of adequate technical
SUITABLE
MEDIA equipment must always take priority over personal protection equipment, make sure that the workplace is
9.
Niosh - Registry
of Toxic
of Chemical
Substances
PHOSPHORIC
ACID:
riskshould
ofEffects
explosion
on
withair
nitromethane.
May
react
dangerously
with
alkalis and
sodium
well
airedClass:
through
effective
local
or bad
vent.carbon
If suchdioxide,
operations
dopowder
not make
it nebulised
possible
towater.
keep
the borohydride.
concentration of the product
The
extinction
equipment
be aspiration
of the
conventional
kind:
foam,
and
ADR/RID
NAcontact
10. INRS - Fiche Toxicologique (toxicological sheet)
below
the permitted
workplace
thresholds
a FOR
suitable
respiratory
tract protection must be used. See product label for hazard details
EXTINGUISHING
MEDIA
WHICH exposure
SHALL NOT
BE USED
SAFETY
REASONS
11.Conditions
Patty - Industrial
Hygiene and Toxicology
10.4.
to(shipping):
avoid.
during
protection equipment must comply with the rules in force indicated below.
None
inuse.
particular.
Carriage
byPersonal
sea
12. N.I.
Sax
- Dangerous
properties
ofprecautions
Industrial Materials-7,
1989 Edition
None
in
particular,
however
the usual
used for chemical
products should be respected.
HAND PROTECTION
13. ECHA website
hands
witharising
category
(ref.substance
Directive
89/686/EEC
5.2.Protect
Special
hazards
fromII the
or
mixture. and standard EN 374) work gloves, such as those in PVC, neoprene, nitryl or
IMO
Class:
NA
10.5.
Incompatible
equivalent.
The materials.
following
should beINconsidered
when
work glove material: degradation, breakage times and permeation. Work glove
HAZARDS
CAUSED
BY EXPOSURE
THE EVENT
OFchoosing
FIRE
Marine
Pollutant.
NO
PHOSPHORIC
ACID:Warning
Metals,
strong
alkalis, aldehydes,
sulphides
and
peroxides.
Signal
resistance
to preparations
should
be (carbon
checked
beforetoxic
use,
as it canproducts,
be unpredictable.
Gloves’ limit depends on the duration of exposure.
Do
not words:
breathe
combustion
products
oxide,
pyrolysis
etc).
Note for users:
EYE PROTECTION
MSDS EPY 1002
NITTY-GRITTY S.R.L.
Tig.Bomar - TIG BOMAR
EN
Revision nr.1
Dated 30/10/2012
Printed on 4/12/2012
Page n. 2 / 7
Hazard statements:
H319
H315
Causes serious eye irritation.
Causes skin irritation.
Precautionary statements:
P264
Wash . . . thoroughly after handling.
P280
Wear protective gloves / protective clothing / eye protection / face protection.
P302+P352
IF ON SKIN: Wash with plenty of soap and water.
P332+P313
If skin irritation occurs: Get medical advice / attention.
2.3. Other hazards.
Information not available.
3. Composition/information on ingredients.
3.1. Substances.
Information not relevant.
3.2. Mixtures.
Contains:
Identification.
Conc. %.
PHOSPHORIC ACID
13,5 - 15
CAS.
7664-38-2
EC.
231-633-2
INDEX. 015-011-00-6
CITRIC ACID
4 - 4,5
CAS.
77-92-9
EC.
201-069-1
INDEX. -
Classification 67/548/EEC.
Classification 1272/2008 (CLP).
C R34, Note B
Skin Corr. 1B H314, Note B
Xi R37/38, Xi R41
Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335
T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N =
Dangerous for the Environment(N)
The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.
4. First aid measures.
4.1. Description of first aid measures.
EYES: Irrigate copiously with clean, fresh water for at least 15 minutes.
Seek medical advice.
SKIN: Immediately wash with plenty of water. Remove all contaminated clothing. Obtain immediate medical attention. Wash contaminated
clothing separately before using them again.
INHALATION: Remove to open air. If breathing is irregular or stopped, administer artificial respiration. Obtain immediate medical attention.
INGESTION: Obtain immediate medical attention. Induce vomiting only if indicated by the doctor. Give nothing by mouth to an unconscious
person.
4.2. Most important symptoms and effects, both acute and delayed.
For symptoms and effects caused by the contained substances see chap. 11.
4.3. Indication of any immediate medical attention and special treatment needed.
Information not available.
5. Firefighting measures.
5.1. Extinguishing media.
SUITABLE EXTINGUISHING MEDIA
The extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulised water.
EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS
None in particular.
5.2. Special hazards arising from the substance or mixture.
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc).
MSDS EPY 1002
NITTY-GRITTY S.R.L.
Tig.Bomar - TIG BOMAR
Revision nr.1
Dated 30/10/2012
Printed on 4/12/2012
Page n. 3 / 7
EN
5.3. Advice for firefighters.
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for
health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of
contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Hardhat with visor, fireproof clothing (fireproof jacket and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof
and antistatic), a depressurised mask with facemask covering the whole of the operator’s face or a self-respirator (self-protector) in the event
of large quantities of fume.
6. Accidental release measures.
6.1. Personal precautions, protective equipment and emergency procedures.
Wear appropriate protective equipment. Send away individuals who are not suitably equipped. Use breathing equipment if fumes or powders
are released into the air. Block the leakage if there is no hazard. Do not handle damaged containers or the leaked product before donning
appropriate protective gear. For information on risks for the environmental and health, respiratory tract protection, ventilation and personal
protection equipment, refer to the other sections of this sheet. These indications apply for both processing staff and those involved in
emergency procedures.
6.2. Environmental precautions.
The product must not penetrate the sewers, surface water, ground water and neighbouring areas. Dilute the product well with water after
collection.
6.3. Methods and material for containment and cleaning up.
For liquid products, suck into a suitable container (made of material not incompatible with the product) and soak up any leaked product with
absorbent inert material (sand, vermiculite, diatomeous earth, Kieselguhr, etc). Collect the majority of the remaining material and deposit in
containers for disposal. For solid products, use spark proof mechanical tools to collect the leaked product and place in plastic containers. If
there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Contaminated
material should be disposed of in compliance with the provisions set forth in point 13.
6.4. Reference to other sections.
Any information on personal protection and disposal is given in sections 8 and 13.
7. Handling and storage.
7.1. Precautions for safe handling.
Before handling the product, consult all the other sections of this material safety data sheet. Do not eat, drink or smoke during use.
7.2. Conditions for safe storage, including any incompatibilities.
Normal storage conditions without particular incompatibilities.
7.3. Specific end use(s).
Information not available.
8. Exposure controls/personal protection.
8.1. Control parameters.
Name
PHOSPHORIC ACID
Type
TLV-ACGIH
OEL
OEL
WEL
Country TWA/8h
mg/m3
EU
IRL
UK
1
1
1
1
ppm
STEL/15min
mg/m3
ppm
3
2
2
2
8.2. Exposure controls.
As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace is
well aired through effective local aspiration or bad air vent. If such operations do not make it possible to keep the concentration of the product
below the permitted workplace exposure thresholds a suitable respiratory tract protection must be used. See product label for hazard details
during use. Personal protection equipment must comply with the rules in force indicated below.
HAND PROTECTION
Protect hands with category II (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in PVC, neoprene, nitryl or
equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove
resistance to preparations should be checked before use, as it can be unpredictable. Gloves’ limit depends on the duration of exposure.
EYE PROTECTION
MSDS EPY 1002
NITTY-GRITTY S.R.L.
Tig.Bomar - TIG BOMAR
Revision nr.1
Dated 30/10/2012
Printed on 4/12/2012
Page n. 4 / 7
EN
Wear protective airtight goggles (ref. standard EN 166).
SKIN PROTECTION
Wear category II professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body with
soap and water after removing overalls.
RESPIRATORY PROTECTION
If the threshold value (if available) for one or more of the substances present in the preparation for daily exposure in the workplace or to a
fraction established by the company’s prevention and protection service is exceeded, wear a mask with an B or universal filter, the class (1, 2
or 3) of which must be chosen according to the limit concentration of use (ref. standard EN 141).
The use of respiratory tract protection equipment, such as masks like that indicated above, is necessary to reduce worker exposure in the
absence of technical measures. The protection provided by masks is in any case limited.
If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency,
or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained,
open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half
mask or mouthpiece (ref. standard EN 138).
9. Physical and chemical properties.
9.1. Information on basic physical and chemical properties.
Appearance
liquid
Colour
light green
Odour
odourless
Odour threshold.
Not available.
pH.
Not available.
Melting or freezing point.
Not available.
Initial boiling point.
Not available.
Boiling range.
Not available.
Flash point.
>
60
°C.
Evaporation Rate
Not available.
Flammability of solids and gases
Not available.
Lower inflammability limit.
Not available.
Upper inflammability limit.
Not available.
Lower explosive limit.
Not available.
Upper explosive limit.
Not available.
Vapour pressure.
Not available.
Vapour density
Not available.
Specific gravity.
1,16
Kg/l
Solubility
soluble in water
Partition coefficient: n-octanol/water
Not available.
Ignition temperature.
Not available.
Decomposition temperature.
Not available.
Viscosity
Not available.
Reactive Properties
Not available.
9.2. Other information.
Information not available.
10. Stability and reactivity.
10.1. Reactivity.
There are no particular risks of reaction with other substances in normal conditions of use.
PHOSPHORIC ACID: decomposes at temperatures over 200°C.
10.2. Chemical stability.
The product is stable in normal conditions of use and storage.
10.3. Possibility of hazardous reactions.
No hazardous reactions are foreseeable in normal conditions of use and storage.
PHOSPHORIC ACID: risk of explosion on contact with nitromethane. May react dangerously with alkalis and sodium borohydride.
10.4. Conditions to avoid.
None in particular, however the usual precautions used for chemical products should be respected.
10.5. Incompatible materials.
PHOSPHORIC ACID: Metals, strong alkalis, aldehydes, sulphides and peroxides.
MSDS EPY 1002
NITTY-GRITTY S.R.L.
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Revision nr.1
Dated 30/10/2012
Printed on 4/12/2012
Page n. 5 / 7
EN
10.6. Hazardous decomposition products.
In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released.
PHOSPHORIC ACID: phosphorus oxide.
11. Toxicological information.
11.1. Information on toxicological effects.
Acute effects: stinging eyes. Symptoms may include: rubescence, edema, pain and lachrymation. Contact with skin may cause: irritation,
erythema, edema, dryness and chapped skin. Vapour inhalation may slightly irritate the upper respiratory tract. Ingestion may cause health
disorders, including stomach pain and sting, nausea and sickness.
PHOSPHORIC ACID
LD50 (Oral):
LC50 (Inhalation):
LD50 (Dermal):
CITRIC ACID
LD50 (Oral):
SODIUM CITRATE
LD50 (Oral):
1530 mg/kg Rat
> 0,85 mg/l/1h Rat
2740 mg/kg Rabbit
3000 mg/kg Rat
1700 mg/kg Rat
12. Ecological information.
Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or
sewers or contaminate soil or vegetation.
12.1. Toxicity.
Information not available.
12.2. Persistence and degradability.
Information not available.
12.3. Bioaccumulative potential.
Information not available.
12.4. Mobility in soil.
Information not available.
12.5. Results of PBT and vPvB assessment.
Information not available.
12.6. Other adverse effects.
Information not available.
13. Disposal considerations.
13.1. Waste treatment methods.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product
should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
14. Transport information.
The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail
(RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.
Road and rail transport:
ADR/RID Class:
NA
Carriage by sea (shipping):
IMO Class:
Marine Pollutant.
NA
NO
MSDS EPY 1002
NITTY-GRITTY S.R.L.
Tig.Bomar - TIG BOMAR
Revision nr.1
Dated 30/10/2012
Printed on 4/12/2012
Page n. 6 / 7
EN
Transport by air:
IATA:
NA
15. Regulatory information.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.
Seveso category.
None.
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.
Product.
Point.
3
Substances in Candidate List (Art. 59 REACH).
None.
Substances subject to authorisarion (Annex XIV REACH).
None.
Healthcare controls.
Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks
related to the workers' health and safety are modest and that the 98/24/EC directive is respected.
15.2. Chemical safety assessment.
No chemical safety assessment has been processed for the mixture and the substances it contains.
16. Other information.
Text of hazard (H) indications mentioned in section 2-3 of the sheet:
Skin Corr. 1B
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
H314
H318
H315
H335
Skin corrosion, category 1B
Serious eye damage, category 1
Skin irritation, category 2
Specific target organ toxicity - single exposure, category 3
Causes severe skin burns and eye damage.
Causes serious eye damage.
Causes skin irritation.
May cause respiratory irritation.
Text of risk (R) phrases mentioned in section 2-3 of the sheet:
R34
R36/38
R37/38
R41
CAUSES BURNS.
IRRITATING TO EYES AND SKIN.
IRRITATING TO RESPIRATORY SYSTEM AND SKIN.
RISK OF SERIOUS DAMAGE TO EYES.
GENERAL BIBLIOGRAPHY
1. Directive 1999/45/EC and following amendments
2. Directive 67/548/EEC and following amendments and adjustments
3. Regulation (EC) 1907/2006 (REACH) of the European Parliament
4. Regulation (EC) 1272/2008 (CLP) of the European Parliament
5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament
6. Regulation (EC) 453/2010 of the European Parliament
7. The Merck Index. - 10th Edition
8. Handling Chemical Safety
9. Niosh - Registry of Toxic Effects of Chemical Substances
10. INRS - Fiche Toxicologique (toxicological sheet)
11. Patty - Industrial Hygiene and Toxicology
12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
13. ECHA website
Note for users:
MSDS EPY 1002
NITTY-GRITTY S.R.L.
Tig.Bomar - TIG BOMAR
Revision nr.1
Dated 30/10/2012
Printed on 4/12/2012
Page n. 7 / 7
EN
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the
suitability and thoroughness of provided information according to each specific use of the product .
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health
and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Changes to previous review:
The following sections were modified:
02 / 14.
MSDS EPY 1002