MSDS - Version: 1

Transkript

MSDS - Version: 1
MSDS - Version: 1.2
Product name : RAL5017E/P-PARLAK
Product code : KC60905017
Product date : : 26.07.2013
Section 1 - Product and company
identification
MANUFACTURER'S NAME
KC Kimya Ticaret ve San.A.Ş
Beylikbağı Mah.E 5 Güney Yanyol
Cad.No:50 Gebze
Kocaeli/ Türkiye
PRODUCT CLASS
Powder coating. Applied by
electrostatic spray
PRODUCT CODE & TRADE NAME
KC60905017
RAL5017 E/PPARLAK
MATERIAL SAFETY DATA SHEET
EMERGENCY TELEPHONE NO
I+90 262 653 03 52-04 52-05 52
NFORMATION TELEPHONE NO
+90 226 653 12 52
DATE OF PREPARATION
Section 2 - Composition of
ingredients
INGREDIENT NAME
: 26.07.2013
CAS Number
PERCENT BY WEIGHT
BISPHENOL A/EPICHLORHYDRIN POLYMER 25036-25-3
1~5
BARIUM SULFATE
007727-43-7
15 ~ 40
TITANIUM DIOXIDE
013463-67-7
7 ~ 13
CARBON BLACK
001333-86-4
< 0.5
NUISANCE DUST
N/A
As generated
Section 3 - Hazards Identification
ROUTES OF EXPOSURE
Exposure may be by inhalation, skin, eye contact. To minimize exposure, ventilation and personal protective equipment is
recommended. Avoid breathing
vapor or mist. Avoid contact with eyes, skin, and clothing.
SHORT TERM & LONG TERM EFFECTS
- Short term effects Cause respiratory tract, skin and eye irritation.
Additional effects may include lack of sense of smell, nausea, headache, drowsiness, drunkenness, tingling sensation, liver and
kidney and nerve damage.
- Long term effects In addition to effects from short term exposure, ringing in the ears, stomach pain, bloody vomit, difficulty speaking, chest pain,
irregular heartbeat, fainting,
loss of memory, blood disorder, brain damage, coma and heart failure may occur.
Extremly high concentration vapors may cause person to unconsciousness or death. Drinking alcohol may worsen the effects.
Prolonged overexposure to solvent may cause liver, kidney, brain and nerve system damage and reproductive harm.
Section 4 - First Aid Measures
INHALATION : Remove from exposure area to fresh air immediately. Perform artificial respiration if necessary.
Keep person warm and at rest and get medical attention immediately.
EYES : Wash eyes immediately with large amounts of water occasionally lifting upper and lower lids, until no evidence of chem ical
remains
(at least 15 ~ 20 minutes). Get medical attention immediately.
SKIN : Remove contaminated clothing and shoes immediately. Launder before re-use. Wash affected area thoroughly with soap and
water until no
evidence of chemical remains(at least 15 ~ 20 minutes). Get medical attention immediately.
SWALLOW : Extreme care must be used to prevent aspiration. Do not induce vomiting. Get medical attention immediately.
Section 5 - Fire Fighting Measures
Hazards from combustion products:
On burning will emit toxic fumes, including those of oxides of carbon and oxides of nitrogen .
Precautions for fire fighters and special protective equipment:
Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of
combustion.
Minimize dusting during use. Keep all equipment clean and properly grounded to avoid static electricity discharge.
Suitable Extinguishing Media:
Fine water spray, normal foam, dry agent (carbon dioxide, dry chemical powder).
Section 6 - Accidental Release Measures
Emergency procedures:
If contamination of sewers or waterways has occurred advise local emergency services.
Methods and materials for containment and clean up:
Wear protective equipment to prevent skin and eye contact and breathing in dust. Work up wind or increase ventilation. Cover
with damp absorbent
(inert material, sand or soil). Sweep or vacuum up, but avoid generating dust. Collect and seal in properly labelled containers o r
drums for disposal.
Page 1
MSDS - Version: 1.2
Product name : RAL5017 E/P-PARLAK
Product code : KC60905017
Product date : : 26.07.2013
Section 7 - Handling and Storage
HANDLING
Keep all equipment clean and properly grounded to avoid static electricity discharge. Keep work areas free of dust. Avoid excessive
skin contact.
Do not ingest or inhale. Keep out of the reach of children.
STORAGE
Keep containers sealed and avoid static electricity discharges.
Section 8 - Exposure controls / Personal Protection
Occupational Exposure Limits
BISPHENOL
A/EPICHLORHYDRIN
POLYMER
BARIUM SULFATE
TITANIUM DIOXIDE
CARBON BLACK
NUISANCE DUST
ACGIH TLV
5.00 mg/M³
10.00 mg/M³
10.00 mg/M³
3.50 mg/M³
10.00 mg/M³
ACGIH TLV-C
N/A
N/A
N/A
N/A
N/A
ACGIH STEL
N/A
N/A
N/A
N/A
N/A
OSHA STEL
N/A
N/A
N/A
N/A
N/A
OSHA PEL
15.00 mg/M³
5.00 mg/M³
10.00 mg/M³
3.50 mg/M³
N/A
ENGINEERING CONTROLS
Provide sufficient ventilation in volume and pattern to keep air contamination concentration below applicable OSHA permissibl e
exposure
levels or ACGIH’s TLV TWA limit.
RESPIRATORS
Use properly fitted NIOSH/MSHA approved gas & vapor respirators, or conventional respirators, or negative pressure respirators
or particulate respirators,
or FFR (filtering facepiece respirator) to avoid breathing dust.
OTHER CLOTHING
PROTECTIVE GLOVES: Recommended to avoid skin contact.
EYE PROTECTION: Goggles or safety glasses w/side shields recommended.
OTHER PROTECTIVE EQUIPMENT: Protective overalls recommended. Remove and wash soiled clothing.
Section 9 - Physical and Chemical Properties
Physical state :
Powder
Colour :
Coloured
Odour :
Slight
Solubility:
Insoluble in water.
Specific Gravity :
1,20 ±0.05 gr/cm³
Relative Vapour
Not applicable
Density(air=1):
Not applicable
Vapour Pressure (20 °C): Not applicable
Flash Point (°C):
Not available
Flammability Limits (%) Not available
:
<1
Autoignition
Insoluble
Temperature (°C) :
Not available
% Volatile by Weight : Not applicable
Solubility in water (g/L) :
Melting Point/Range
(°C) :
Boiling Point/Range (°C)
:
Section 10 - Stability and Reactivity
Chemical stability :
Stable under normal conditions of use.
Conditions to avoid :
Avoid contact with foodstuffs. Avoid exposure to heat, sources of ignition, and open flame.
Incompatible materials :
Incompatible with oxidising agents.
Hazardous decomposition products :
Oxides of carbon. Oxides of nitrogen.
Hazardous reactions :
Hazardous polymerisation will not occur.
Section 11 - Toxicological Information
EFFECTS OF EXPOSURE : See section 3
ACUTE TOXICITY DATA :
1) TITANIUM DIOXIDE
Section 12 - Environmental Information
Ecotoxicity
LD50(Oral-rat)
LD50 9500. mg/kg
Do not allow to enter soil, waterways and waste water channel.
Section 13 - Disposal Considerations
Disposal methods:
Manage or dispose in accordance with local, state and national regulations.
Page 2
MSDS - Version: 1.2
Product name : RAL5017 E/P-PARLAK
Product code : KC60905017
Product date : : 26.07.2013
Section 14 - Transport Information
Road and Rail Transport
Not classified as Dangerous Goods by the criteria of the International Freight Transport Association (FTA Code) for transport by
Road and Rail; NON-DANGEROUS GOODS.
Marine Transport
Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code)
for transport by sea; NON-DANGEROUS GOODS.
Air Transport
Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods
Regulations for transport by air; NON-DANGEROUS GOODS.
U.S. Department of Transportation (DOT)
Not in the IATA dangerous condition.
Shiping Name: by plane, by ship, by truck
Hazard Class: None
ID Number: None
Packing group: None
Labels: Not dangerous material
Section 15 - Regulatory Information
Classification :
This product has been classified in accordance with the hazard criteria of the 91/155/UE.
Hazard Category :
T : Toxic
Xi: Irritant
Risk Phrase(s):
R20/22: Harmful by inhalation and if swallowed.
R36: Irritating to eyes.
R42/43: May cause sensitisation by inhalation and skin contact.
R46: May cause heritable genetic damage.
Safety Phrase(s):
S22: Do not breathe dust.
S24/25: Avoid contact with skin and eyes.
S36/39: Wear suitable protective clothing and eye/face protection.
Section 16 - Other Information
The data given here is based on our current knowledge and experience. The purpose of this safety data sheet is to describe the
products in terms of their
safety requirements. The data does not signify any warranty with regard to the products properties.
Page 3

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