Oxalic Acid: Material Safety Data Sheet

OxalicAcid: MaterialSafetyDataSheet
arrii..1rid l)ih)ihr..
synonym(s)
CASNtrmber
llthr..,l. ic Ac
l)il_rLldr.
6l5l-56-6
(to(]H),.:If,o
Manutuclwe. / Suppli$
144-62-7
6r53-56-6
l!_cgi'r3rrr!i$*lT(
r i ! F ! , K c j i . a l c n i l ! . 1L r . , L t !
J r . a i : r ' ! a f N o N , S i i l i l z i u a i r . i ! ) . . t t e btcj oj t i . r . { t h t r d
+8(r-3lr-tar:ir702
ilormltior otr ltrq.edlents
EINECS\umber
ChebicrlNrme
% byweigbt
205-614-r
Ora.r!Acrd.
rnh)Jrou.
unlislcd
n
OxalicAcid Dihydmre
.. . :lar?:,
99,5-100
f,nersercy Overview:
b'!rs !o lllc skii. cycs ann r.sfir.r!_r n!ci.l{,bnfr1
ilri slir Va)!a!J.[&r!]
;ri!isL.
il 'rhrled,I.l:titi.d
PoteDtist Herlth Eff.cts
RoutesofEntry:
h h . l R r i r 4 l i g e s t i o n , I t y . C n n l $ t a n d S kai o n r r c t
TaEetor8ans:
].ir-.s SUtr,li.sni $ry S)slenjanJ Kidr.:]i
SkinContact:
Sltincoftr.imay.rus! i
tr:it
{ilh s_rnltih ntrc.jn.ii i\,.rltirg it.tirr:
lrf..rracl fr.] ..rsr irlr.rk \i1h s)artn)r\ d cd css.srlethrg.irchnrg
ar'l raid i--:.rsc Conrealirjti !_r.
lnhalarionnfo\nlc ^cnl f( uc* ,.i.!iir of'csfiaio^rrner, r(lrta x!!
l)!.1i. ..1cjd( ioir. {r liL!l! nsj gn* inai,bc ar|Jl.]n!estjr'r Drt .auje
{ ; ' ! r ' r . n t r j r i l i ! , 1 . , s .n a u s c ?! o, i n i ( i n gs, h r * n n dc o . r ! t : n r s . O r a l i . A . i d
[rxD !s a:!i.i!.1 irnr t|. bh.i
]:'.tririr ()"r.tin. tul.irm Or.lN:r tr!s
l n r n . d i r i g h !p r c i t i f r ! i n 1 l . t l a I r u b i t , \ .
i t ' , L l i , , r . f O \ . i L . , ! o ( lo r . r . l ! r ! p u i u Jo t . i r r . n d ) c a D sicr , l j r . r n r , r n , )
0 1i . \ f i r i r a o r l ? . : . t i l n l i g h l r . s ! [ n r $ r i g h r t o r s I r ; n a t a ] s o r . s l t jLn
l r f. l i r l ; r s i s( r h . i n r r a l i o ! i a M t n r r ys t L , n ! s ) .
Non..
Explanation
of
Carcinogenicity:
Medicalconditions
i,r,!!n!wiLh ph.xisri,l! o).csorrtir .ondiridrsorirpr:reit p!trorr.:
a88nvaledby €xposui€rliurc1i.trrm_v-'
b. rnoresr!.ttible t. rhc.1Ia(* ot thisfrldu.i
-t-
rii-es.l..i".1.:.,:r'--"':'-::
Eyes:
h..r.
0 1c . . ! i r .
.
-.:X,
w m c d u L . l J -i l ! : h . : ! r . l l i a i rp l c . t t o { * l t i r
.
;X
1ir itt(ia tj
rni'rut6. C.i rrciical aid imlrrilar.[i.
Skin:
l..rri. oi con1|c1i$rr.lfur.l) ]lrir iki! riri: f:rnr ot \at!r lif iitt.rr: lj
. ! ! ! . J i * h i l . E n a r ri r g . . ' l l r ! . i r r ( d c [ r t h i r i g
rn.i:].!:. (ietnrcdjcal;id
irmodierjh. 1\ eil ! lr hing b.ln.c te$.
Il srrr:l!u1l. do \Oi i uc.lonritiDe.It cons.iousgircw{$, nilk or Nljtl ot
N l a s n c s i\a: .' . r * i ! r a i ! $ i r ! b I n n , r h r on n r ! r : " , i , i i , r j p . d d n a t r l ta
II inhalcd-r!rno!c t{,iis| .i. lf 0or 5.!rliigri!c
r i l i l i c i a lr ! f i , r r i { x rl .i '
bEaLhingis diticull {i!c OxIg.n. tlt tietii.alaid
Aulo lgnilion
ExplosionLimits
NFPA Rating
r..r\rlr.:\crl is .0firrr.illi bcloi! ll)l'C t?lJ.l:). DccorUio!iLiorrir,lrcL.
i n cn d . . . 1 1 . 1 n , ) n n \ i d cl r d l l n n i ! { c i dr h i . h a f c | l ] ! r
d I l i n D x b i . .t t r a 0 i s
c\rk^i'.:f i th rfro.g ori(lizilg dr]r.,jaisitrd sonr. !t|cr !onn.!rds.
U s . \ t . 1 . . r p ( , v .( l ( c h c n n c a(l1. . { i , . nl ) i O \ l d c! r a l . . n , , l t r J . N :I r a n o , r . r . ,
on moilcr i)r!li. A.iJ rtar .rr!. r:.iirrg.
I l.i:1li: l: |larnmabilil!: lr Rcaclirit"-:1r
Fir fight!r::nr!ln {cdr r lirlt tforc{i}c gcir. \!irt] | sllFconlxinfdbr".thi|S
afiui1nr n]rL lirll ticf irie.c olcrat.dtu losliv. Fr.ssuR'node_
14oLc
.orlri'r.is liln ilrt aor ii ir cx! bc ddnclljlhoor rsk L'!.r.terrokrcp ir.cxpos!Ccunrnincrx
cool.
,riix*X' .i.. '
\:!!rjtarc !rca oi t.al
rjLjljze
GenenlInfomation: l{. olc ail n'!,aes.ii1lfilior.
if s..tin
tr. tccl ir'. c ldltjrg and cau ipnrcrl iis slt.ill.l
.r slit1.
re.o,r.,.ir:t.d
I
S p i l l s : ( i l r alih r s t . i i lt i r i t r t r r r L l r a l a o . r r i n t i i \ t 1 c .rsl 6c r i r r { r l h r x i r r j s . ! o r i i r k i n g L ( , o trsn i
c q t r i p n r l t l r i c k! f i f l L l l i ' ! . c o l c r yf s l o s r l a i d f t a r c i n . l o s < t c ! n | 1 i n . r . s p i t i r l r e a i i . t . k s h e d
rillr{e.ll(rilec($ashrrn.r:.riitjttu!.ddtspo!l.lVanr.t:i|!r.itrtrouldbcna.orit.ilo}ilh!t.
A
l.dcral.sialcandlocrl..!rrn.r.rtli
rcguhrilus.
Ilandling:
r [ i n o f o n . ] . r i ] i . 9 .N l i i r n i z . d L s 3
r c n d . t i o nr r d i c . u i r u t a r i o n .
Sto'! i.. Lo.. d,_r.
rnd xrlhcnlihl;il rir. $.d liotrr heati.it tr..ht)dibtc
srbsr....s lNl$ s..ti.N la). Kc.t ..rrLiri.L .igh!1,!closc<l
EIgineerlngCoDtrols:
Faciliricss[l,nngorntilizing rhenaterialshouldbe equippedwithan eyewashfacility anda saaelyshower
gen€mlor localexhairs!ventilation
Useadequate
to keepaitome concenlration
belo$ the permissible
ErDosur.Umits:
Oalic Acid.anhydrous
TnrgnnjSI Ll,
lngi'm: llv-Sl_lll.
,ngnn,'l_1.\'-S'llu.
J l t r n g l r n r) D I - l l( N 0 l S I l l
Onlic Acid Dihydmte Nol I isicd
NorIist.il
NorList.d
Personal Protective Equipn€rt:
ils..h.)ni.J sdttl gdg-sl.!o, e.!cglasscs.
A frc. shi.ld ,!r !lso benclcssir!.
i{!drlain i}.{'is inNr&r;nrnd sildts|!r0n ii rhuinmrcdi{..n.rt arua.
Skin:
l\eir inrpcr\'iorsph1tr1\,r cldthi|e in.lulirl?tmn
bootsandrubbcr:Ll8.sas
i,'selocxl r.itiJalion ilirrting is x !!)bl.nr, $Inxhuin af lcv.ls b.lo* rb.
(.ori .'r ded.\.os Lrr Ijtnll.
i\ffl\Ned rcspi'rlos shrt(l be uscltif airnoncconccirirlior ercccds
'tcommend.narii. r.f cnergclcjcs.r !6 r$c.s Nh.ie the ealrrsur Lr'.1s t
ror k.r$i. !tr r lirl{ncc piecet0sirilr-prcssu., rn suptli.a e3pi$r.r..
WiililNi;: Air-pni,),ir)gr$pir.lon do orrolec! rvojli.fs h oxl ge|-dcficl.il
PhysicalSiale
Solid
$Jh(c dl srrllir. t.!ti!f
Odor
(co0Hlr.2H,o
120.071,1[jrtlnlc)
pH
l.: (0.1Msolurhnni \lltler)
IrJsilran0.rr(jt .r llg 'rr 2L)'(
{i;8'}j)
1..1{,1ir l)
Melting Point
l.t+ lar0'C{100-320"::)
I01.5'{'{2lJ'f)
:57.C
Decompositio!TEnlPc.dLure
r 8 9 . 5" C
Solubiliiyin water
Solubilityin Ethanol
Solubilityin DicthylEthef
Specificg6vity
1 1 . :gl / 1 0 0& 1 { : i " l )
2 - l- ,g : l { } ! $ i ( 1 < ? C )
i . i t ! , i 1 1 1u0r l ( 1 5' l l j
| ,! !,rcirr (anhydrausl
1.65-rgic,' (;ih j.'d.rrc)
Acidity
Dissociation
constant(pK,
pK,
1 . 2 1p, K r = r l . l 9t z j c d l
Rh.nrbicianhldous). :\'1('nncll!lc
!l ib!drirol
-3-
Stability:
srrblc oodero,dhl.t conditior'5
.luse aDdslorrlge.
s!rungo\idizi.g irg.n|:\(such.s pgrhlomt.s_lrrc\id!'s. pcmargara&,s'
chltl!1.t, trrtEJcs.
c! b.inc. bronir! anLlllirorii.l: h!Fofltorirc. SliverrDd irs
componDds,
sLongn,kalis..hloircs and1ur'!J,ytdtuolot- sil.r !1deni rcocrirbs
I li:al.ignilionsou!.r drd ln.onpuibititi.!.
carbotrnn$nde. Cirbo!dioxide.irdra! rri,l_acid s'$1. rrd nrnrcs_
Ilas rol b.. Rforted.
Cts Xu'nler:
144-62-7
6153-56-6
fl.,1*S.g+S:'.3i::nr*iuil|.l,
i |liw
-Rllifs Nunber..ll' '
.....,r.::r-'
R02450000
..
.:"..' .
;
,' ...,,.-,
.,'
Unlisted
ACI,ITEI1O)qCITY DATA:
Route/O.grlilm
Dore
Effect
I n l E p e r i l o n e r L M o J r eI e , h adl o s e , 5 0p e r c e hkri I ) : 2 ? 0m g / | \ g \ R
OrafDos
Oral-Rat
lowestpublishcd
lethaldose:1 gn/kg
N/R
lelhaldose(50 perc€ntkin):7500ns&s N/R
castloinrestinal:
Chaneesjn sruciurc
o.tunctionof esophagu
lowestpublished
lethaldose:600mg/kgcdiroinresrinatHypemotiliry,
dimhea
l o w e np u b l i s h el d
e t h a l d o s er 2
:lng/kg
caslrcintestinat:
Otherchdges
N/R
l o w e spt u b l i s h ol d
c t h a l d o s e : 7m
5 7g / k 8 N / R
Iethaldose(50 percentkill):1400ing/kgN/R
4-
CARCINOGENTCTTY:
OxalicAcid,anhydrcxsNor Ustedby ACGIH, IARC,MOSH, NTp or OSHA.
oxalic Acid Dihydl?te Nor Listedby ACGIH. IARC,NIOSH,NTp or OSHA.
EnvironDedtll Fatc:
Biodegmdation
Itcldjh anrdegndslil.
BOD5
( j . 16 n r 8 , l
coD
0 ll *r!:l
BOD5/CODmtio
0.89
BCF
0.ti
Frotoiicityl
LC50
4000ng/]. ?l lrNlrs.l:ish(Rluceilll.1000rnrr 0.J hods. Fish(coid
|ish). 100rrq 0.3 bo!r$, Irilh{Tio.,
5330ftg,'l, tt I'orN, Arltr1bi$(Cl!\!ed -foudl
I:lar,tingr1,13 houN.CiNtucarrs{WdrciFIe!)
l5O0r'.9r'L.1n.n6. Alea.
EC50
Disposalshouldbedonein accordancervilh
local,srateandfedemlresulations.
tMo
I]S DOT
P r o p eSr h i p p : n g . ' . \ . . : o l L . A . i . l : r 'o. r y n . .
Name
NO.S.{OxoltcA.id_Djh-ydE.c)
uN Nunb€r
3261
HazaldClass
E
Packingcroup
JII
ft n!!iv!. Sdid, ^.idic, Organj!N.0.S.
((, li! Acli. Dih_ln8t)
:l?61
II
C'lsssifcatioD rnd hbelirg informrtion lD accordancowith L
Classification
dtr€ctiv€s
\r: l? I /?2
Ii21"l:
llarml!1tr corticr ri*r skr ekl il'sqrllo$rd
52
Sl/25
Kc.p or'rll Da.h olchilden
A\oi.t clnrrcr $'iih skin a,rdlJes
l l ; ( : l . l l >( l h . i . n i D . i . S h . . 1 -l . - S l S
(l ,ri*l l oricilr nndrcs!n Aquntic{l.garisn$ ;n lAr" pcstlcidcsde|dhs.
Cl.
i.d t(tllui ctuLuidl)-, Ctrradia|cc]rt! li)r occupali({uti tr0althurdsrlc!]_
IiSDS arailabl.on th.ir:.mc1
I-.gend:
CAS
Ch.mi..l 1a{|iot Sc,\,icc
EINECS
NFPA
flutupcrn tiffrlrry nlllxirtiog ( I dnrr.liil ChenicrI srirstaft.
i! rio,ril lrirel,m1c.!idr,lrsditr.ior (lrSA)
OSHA
O.luparklnrlSatar & Ihrllf Adnrilillmii.n (i:SA)
NIOSH
\rrldzl
ru(llD
ESIS
lnc ati('b,llL!rillrrr lli.rical lnibin]aLion
L)lr.nA.
lirrdtern ch.r.icri S{nsrrnc.str!l;rh!ti!i S:;.ni
ACIGH
.{i'crift,t.nl!r!..colCoy.rrdroiralln(lr:i.j.:lt:;Lr.li:i
IARC
lolcdDrnrralig.r.]ln,lt€s.arohonr.a!..i
RTECS
ltcgijiD rf Irri. lrfli.l\ or Ch|rlir.l ;rlrr:.icfs
'I
'.
NTP
PAN
l'1srilurrtor Occuprliora I S.liry & il.allh (USA,
USDOT
l ' . s 1 i e i dAe. r i o N} . ' ! l \ ! i i l i ; S A )
llS i)cpi,rlmcn
o rl l i r . i t r r x r n r l
IMO
lnlinraljor.iN{n|i|ir!.OrghiisDrnnr
TLV-TWA
T\rl- - STEL
I_hiGh.lniirnir vlrl1i.
l nr. \\rcighr.dAlrrig! 1A(rt(itt)
lb,csholdI imi{ Vrhc
IDLH
ShoftTcrn trxfosu! I.inn lACICti)
lmnrcdhrellDrngln)|iihiifcanl|.^hhcalcfrr;lllrnr,rt!!iN()tStt)
l D50
|r'.
LC50
EC50
Lcthal con!r.1rdi1)n.nuiing dcalhir -ill'r;
\1.di:nliliJllLvri!ncenrariortlq!i..rr.inlluc.50',tcf.cr)
BCF
llio-con..nlrdtiln tnc1o.
..,.,,.'!|.
The infomationcontainedin fihMaterial SaferyDaiaSheetis believedrobeaccumreandreprcsens
the beslilfomation curently availabletoHebeikejin chemical.,ltd.
However,Hebeikejinch€fticalco.,ttd.
makesno rcpresentation
of lr€trantyofmerchantability
or any oher waranty, ex?rcssorinpli€d, in
resp€ctloLhccuxprchcnsivenessor
adequacyoflhisdocumenr
lbr any panicularnscandshattassunre
no
liabilityrcsultingftom its use.Usersshouldmaketheiroqn investigations
1odeterminerhesuitabilityolthe
infomationfo. theirpa{icularpurposes.lnnoway shalltheconpanybe liablefor any claims,Iossesor
damgesofany thid paftyor for losiprofitsoi exeDplarydamges,howsoevddisihg. ev.n if thoconpmy
h a sb e e na d \ i s c do l r h ep o s s i b i l i toyl - s - c ld m g e \ .
tr>(ffihtffi,m^HK
Ce
ate of Analysis
ItemDescription
lheha^ri^n
O x a l r cA c r d 9 9 . 6 %
n.r-
[r]ar.20.20'11
Test ltems
Standards
Test Results
Total Ac jdity%
9 9 , 6m i n
99 . 6 5
Ash%
0 . 1m a x
0 . 09
lronak
0 . 0 2m a x
0.00'15
Loss on lgnition%
0.08lvlax
0 . 07 9
Sulfate%
01 to]ax
0.08
Chloride
20ppml\4ax
2A
10pprnlllax
10
Eeavy tuleraI
Conclusion:
o u a t i f i e o ,i , l
i-l
{i
L::1.,.':
6 T h F L O O R3 2 | L T O C A T E
. t L ! L O \ D C N E a a r , i7 D R U N I t u K N ( i t c r
R o u n ( 1 0 0 9 : o i h F o o , s h a N g f aK
: e r r yE v e : b , , g rar ( f r . ( e
N.'
!
a -r;
a. r,,[Roac!,esi t]65"- rst
il
.ia(l.1eif.t il com
5.a-ji.
/0!ijlr
!NraFax ,862163539502